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Materials——Hafnium

About Hafnium

Hafnium is a lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Hafnium’s large neutron capture cross-section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors.

Hafnium has good neutron-absorbing properties, and hence it is used in control rods in nuclear reactors, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors. While hafnium nitride is the most refractory of all the metal nitrides, hafnium carbide is the most refractory of all the binary materials. With a melting point of about 3900 °C it is one of the most refractory binary compounds known. Hafnium has been successfully alloyed with several metals including iron, titanium and niobium.

 

Hafnium Specifications
StandardsDescription
ASTM B737This specification covers hot-rolled and/or cold-worked hafnium rod and wire. This specification contains 2 material grades, one sepcifically for nuclear applications (Grade R1) and one for commercial alloying applications (Grade R3).
ASTM B776This specification covers 2 grades of wrought hanium and hafnium alloy strip, sheet, and plate. One sepcifically for nuclear applications (Grade R1) and one for commercial alloying applications (Grade R3).

 

Hafnium Grades
GradeChemical Component %, max
CONHFeMoZrNiSiTiAlTaHF98.8%
Grade R10.0150.040.050.00250.0250.0020.020.050.010.010.010.02remaining
Grade R20.0250.0250.010.00150.010.020.020.010.0050.030.020.3remaining

 

Hafnium Mechanical Properties
FormTest DirectionUTS, PSI(Mpa) min.YS, PSI(Mpa) min.EL(%) min.
RodLongitudinal58(400)22(150)22
PlateLongitudinal58(400)22(150)20
PlateTransverse45(310)25(172)20
StripLongitudinal58(400)22(150)20
StripTransverse45(310)25(172)20

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